1.
Metals
¡¡¡¡The ship is cut apart for the recovery of various materials,
including different kinds of scrap metal. Steel scrap
represents the largest recyclable fraction of the ship.
Scrap metal can be broadly classified as ferrous scrap,
of which the largest proportion is so-called ¡°carbon steel¡±,
and non-ferrous scrap, which comprises scrap of particular
interest due to its relatively high value.
1.1 Hazards
¡¡¡¡Torch-cutting is the most common way of extracting the
metal structure and enabling practical handling for further
treatment. During the process, large amounts of fumes,
smoke, particulates (including manganese, nickel, chromium,
iron, and lead) and material chippings (debris) are generated.
Furthermore, torch-cutting falls into the category of
¡°hot work¡± and consequently, specific requirements to
the surrounding atmosphere are required.
¡¡¡¡Emissions from metal cutting are more
likely to contain air pollutants that have toxic effects
on the workers, exposing their health to risk rather than
having a major air quality impact. Our Company identifies
measures of protection for these cutting operations, both
to avoid the spreading of the contaminants as well as
protecting the workers.
¡¡¡¡Metal exposure through consumption of contaminated seafood
may cause health problems. This is particularly a problem
in areas where workers live nearby ship-dismantling facilities
and where seafood is an important source of nutrition.
1.2 Precautions
¡¡¡¡Prior to any ¡°hot work¡± activities, surface coatings
should be assessed and removed (in the cutting line),
if found to be toxic or highly flammable. All spaces where
torch-cutting is to be conducted, should be clarified
as ¡°safe for hot work¡± prior to start-up. This includes
areas within, on or adjacent to spaces that contain or
have contained combustible or flammable liquids or gases,
as well as accessories connected to spaces that contain
or have previously contained fuel.
¡¡¡¡An area or space is ¡°safe for hot work¡± after concentrations
of flammable vapors or gases in the atmosphere are declared
to be less than 10 percent of the lower explosive limit.
Further, hollow metal containers must be filled with water
or be thoroughly cleaned of flammable substances, vented
and tested prior to cutting. Sufficient ventilation (through-flow)
is required for each hollow structure for the release
of any pressure build-up that might occur during heating.
¡¡¡¡Workers performing any type of metal cutting may be
exposed to damaging bright light, ricochets, noise and
heat. This requires the use of personal protective equipment
(PPE) including suitable eye protection as well as appropriate
hand and body protection. Clothing must not contain flammable
material, and all fire hazards must be moved away from
the object to be cut. Workers subjected to noise levels
of a certain magnitude must use appropriate equipment
reducing the exposure to an acceptable level.
¡¡¡¡The workforce may conduct general metal cutting without
mechanical ventilation or respiratory equipment, provided
that it is not done in a confined or enclosed space and
that metals containing or coated with toxic materials
are not being cut. If sufficient ventilation is not feasible
(to arrange) when metal cutting is performed in confined
spaces, the workers must then use air-line respirators.
Furthermore, someone outside the confined space must maintain
communication with the workers inside in order to provide
assistance and/ or alert in case of an emergency. Workers
cutting metals that contain or are coated with toxic materials,
must use local exhaust ventilation or air-line respirators.
1.3 Waste handling
¡¡¡¡The dismantling facility may recycle scrap metal by
selling it to a resmelting / re-rolling company or a scrap
metal broker. It is important to note that coated scrap
metal that is not recycled should be managed and disposed
of as hazardous waste. Recyclable metal that is intermixed
with non-metallic material can be recovered by the use
of shredders and separators. The remaining non-recoverable
non-metallic materials from the shredding process must
be disposed of as hazardous waste as they may contain
environmentally hazardous substances, such as asbestos
or PCBs. Scrap metal for recycling exported from the dismantling
facility may be contaminated by considerable amounts of
coating products containing toxic or hazardous substances.
Receivers of scrap metal for re-processing should be encouraged
to take action in order to safeguard against pollution.
¡¡¡¡Cable-burning for the recovery of copper wire is highly
hazardous and must be prevented. Operators are strongly
encouraged to separate copper from cable insulation by
other means. Cable insulation should be considered to
contain hazardous substances or substances capable of
producing hazardous substances upon disposal and treated
accordingly if not confirmed otherwise.
¡¡¡¡Anodes are fitted to both the vessel¡¯s hull and inside
tanks in order to protect against corrosion and fouling.
Anodes consist mainly of aluminum (Al) and zinc (Zn),
but may also include small amounts of other metals, such
as copper (Cu), iron (Fe), and mercury (Hg). Anodes are
sacrificed over a space of time and the amount of metals
left when the ship arrives for dismantling will reflect
its history of maintenance. It is likely that most (intact)
anodes will be extracted and sorted for reuse/ resale.
Heavily corroded anodes will be disposed of as hazardous
waste. The removal of the anodes will in itself not generate
any adverse effects on humans or the environment as alloys
are non-toxic in their solid states.
¡¡¡¡Lead (Pb) is toxic, and can be found in batteries, paints
and in components in motors, generators, piping, cables
and others. The detrimental effects of lead upon human
health have been widely known for a long time. Young children
are most susceptible to the toxic effects of lead. Long-term
exposure to even low levels can cause irreversible learning
difficulties, mental retardation and delayed neurological
and physical development. In adults, exposure to lead
primarily affects the peripheral nervous system and can
cause impairment of hearing, vision, and muscle co-ordination.
Lead can also damage the blood vessels, kidneys, heart
and reproductive system.
¡¡¡¡Lead chromate (present in paint pigments) is documented
as a carcinogen both to humans and other organisms. It
may also damage embryo development and cause infertility.
Improper disposal of batteries and paints containing lead
can cause a threat to health as well as to the environment.
¡¡¡¡Mercury is a toxic heavy metal and a persistent, bio-accumulative
pollutant that affects the nervous system. On board ships,
mercury can be found in thermometers, electrical switches,
light fittings and luminescent lamps. Accidental spills
of mercury can lead to dangerous mercury exposure. Consumption
of contaminated fish is also an important source of mercury
exposure. Mercury must be handled as hazardous waste.
2. Oil and fuel
2.1 Onboard
location
¡¡¡¡The vessel¡¯s piping and tank arrangements
will generally contain some quantities of oil, fuel, sludge
and associated residues. Fuel oil may be found in both
integrated and free-standing tanks throughout the ship.
Lubricating oils may be found in a variety of tanks depending
on their individual use. System oils are typically located
in engine room sump tanks, whilst cylinder oils may be
stored in separate purpose tanks. Lubrication/ system
oils may also be stored in drums. Tankers can arrive at
the ship-dismantling facility with a significant quantity
of cargo residues. Further, all tanks may contain a certain
level of sludge.
2.2 Hazards
¡¡¡¡Both petroleum products and non-petroleum oils can have
adverse and well-documented effects on the environment.
Oils and fuels may poison marine organisms and physically
soil the environment (birds, fish, plants, etc.). Oil
spills also threaten natural resources.
¡¡¡¡The primary danger to workers handling oil and fuel
on ships is that of fire and explosions. It should also
be noted that oil and fuel represent certain toxic hazards
and may impose serious health threats to workers if handled
incorrectly. The main exposure routes for the hazardous
components in oils and fuels are inhalation and consumption
of contaminated fish and water. Highly refined petroleum
products are toxic and also represent a fire hazard.
2.3 Waste
handling
¡¡¡¡Oil and fuel removed from ship must
be stored in a safe tank arrangement, ensuring leakage
detection, overfill monitoring and corrosion protection,
in addition to a leakage-collection arrangement. The monitoring
should include record-keeping. Local/ national regulations
require notification to authorities concerning installation
and usage for the storage of flammable or combustible
liquids. Regulations address the issues of fire-protection
and financial responsibilities.
¡¡¡¡Used oil may be defined as oil that
has been refined from crude oil or made from synthetic
materials and which contains physical or chemical contaminants
as a result of being used. Used oil should not be mixed
with other wastes as this may require the entire amount
being managed as hazardous waste. Used oil should be stored
in dedicated tanks or containers and should be labelled
¡°Used Oil¡±. The most environmentally friendly and often
most economical way of managing used oil is recycling.
Oil and oily wastes that are defined as hazardous waste,
either by appearing on a relevant hazardous waste list
or by having hazardous waste characteristics (ignitable,
corrosive, reactive or toxic), must be managed according
to governing national hazardous waste regulations.
¡¡¡¡We have an oil spill preparedness contingency plan that
includes instructions on notification, recovery and normalization.
The plan should be integrated in the general Contingency
and Preparedness Plan (CPP) for the shipbreaking yard.
3
Bilge and ballast water
3.1 Onboard location
¡¡¡¡Bilge water is stagnant water mixed with potentially
polluting liquids, which has drained to the lowest inner
part of a ship¡¯s hull (i.e. the ship¡¯s bilge). Bilge water
may be found anywhere in the ship, and its quantity increases
during dismantling activities due to the accumulation
of rainwater as well as cooling and containment water
used during dismantling operations.
¡¡¡¡Ballast water is fresh, brackish or marine water that
has intentionally been brought on board a ship in order
to adjust the ship¡¯s stability and trim characteristics
in accordance with various operating conditions. It is
critical to safe operations and can involve vast quantities
as cargo holds are often used for ballast water on older
ships (those typically being sent to the recycling yards).
More modern ships have segregated ballast tanks, but even
those may need cargo hold ballast to withstand rough weather.
Further, an empty ship would need larger amounts of ballast
water for safe transport to the recycling yard whether
being towed or steaming under its own power. Ballast water
can be found in various tanks throughout the ship.
3.2 Hazards
¡¡¡¡Bilge water is often referred to as oily waste as it
is usually heavily contaminated with oil and cargo residues,
in addition to other pollutants (inorganic salts, and
metals, such as arsenic; copper; chromium; lead; and mercury).
Given this, bilge water presents an oil pollution hazard
during cutting operations.
¡¡¡¡Ballast water may contain pollutants, such as residual
fuel, cargo hold residues, biocides, oil and grease, petroleum
hydrocarbons, and metals (e.g. iron, copper, chromium,
nickel, and zinc). Ballast water in cargo tanks (oil)
is referred to as dirty ballast water.
¡¡¡¡The transport of large volumes of water containing organisms
from shallow, coastal waters across natural oceanic barriers
can cause massive invasions of neritic marine organisms.
Because ballast water is usually taken from bays and estuaries
with water rich in animal and plant life, most ships carry
a diverse assemblage of aquatic organisms. Aggregate sediments
typically found in ballast tanks will contain living species
which reflect the trade history of the vessel.
¡¡¡¡The arrival condition of the dismantling candidate is
most likely that of ¡°in ballast¡±. The discharge of ballast
water/ sediment species into the coastal sea-area may
be a potential source for introducing unwanted organisms
which threaten the ecological balance in the surrounding
seas and thereby represent a direct threat to biodiversity.
Ballast water can be the carrier of viruses and bacteria
transferred to humans causing epidemics.
¡¡¡¡In order to limit the biological threat represented
by the introduction of invasive species via ballast water,
the vessel should undergo recommended de-ballasting
3.3 Waste handling
¡¡¡¡Bilge and ballast water is transferred to onshore storage
tanks, evaporation pits (ballast water only) or discharged
directly overboard. Regulations apply that specifies permitted
levels of contaminants. The Company will reduce the pollutant
content in wastewater prior to discharge.
4. Paints and coatings
4.1 Onboard location
¡¡¡¡A comprehensive selection of different paints and coating
products are present on board a vessel. These products
are used both on the exterior and the interior and may
have characteristics requiring certain precautions with
respect to the demolition process. The hull is coated
several times during its lifetime in order to prevent
fouling. Fresh paint for maintenance purposes may also
be found on board.
4.2 Hazards
¡¡¡¡Paints can be flammable and may contain toxic compounds
(PCBs, heavy metals (e.g. lead, barium, cadmium, chromium,
and zinc), and pesticides). Paints with metallic compounds
are used to protect ship surfaces from corrosion. Pesticides,
such as tributyl tin (TBT) and organotin are still commonly
in use on wetted hull surfaces in order to prevent fouling.
¡¡¡¡The removal of paints prior to cutting during ship dismantling
may not be necessary unless the process leads to the release
of toxic compounds or if the paint is highly flammable.
Prior to cutting painted surfaces, the dismantling facility
should conduct an evaluation to determine flammability
and toxicity of the paint or coating.
¡¡¡¡Toxic or flammable painted/ coated
steel should be labelled following cutting. Flammable
paints or coatings may be burned away in a controlled
manner. This process requires that provisions for fire-fighting
have been made.
¡¡¡¡Toxic paints or coatings should be removed at a distance
of some 10 cm from the area to be cut. If removal is not
possible or feasible, cutting can proceed provided that
the operator(s) are equipped with respiratory protective
equipment such as air-line respirators. Three methods
are commonly used to remove paints and coatings:
¡¡¡¡Chemical stripping. The application of solvents. Note
that solvents are in their own right, usually hazardous
and will present a use and disposal challenge.
¡¡¡¡Abrasive blasting. A surface is blasted with abrasives
(slag, grits or steel shots). Blasting involves the use
of high-pressure equipment and may potentially be dangerous
if the condition of the equipment applied is not satisfactory.
Periodic checking of pressure equipment/ tools should
be mandatory. Workers¡¯ skin, eyes and hearing are particularly
exposed. Abrasive blast material is a hazardous waste
if the material includes hazardous coating residues or
is made from slag contaminated with arsenic, lead or cadmium.
¡¡¡¡Mechanical removal. Power tools or thermal tools may
be applied. Thermal removal must not be used on paintwork
containing PCB.
¡¡¡¡The methods above may generate emissions
containing compounds of concern, which are also associated
with the potential for causing cancer. The main exposure
route from paint removal is inhalation. Paint removal
activities also generate large amounts of hazardous waste.
¡¡¡¡Most paints and coatings will be exported from the dismantling
facility to steel reprocessing plants via steel plates.
Consequently, the challenges associated with emissions
of polluting substances in the paints and coatings are
transferred to the reprocessing facilities where air emissions
may be easier controlled. The labelling of steel plates
will enable the reprocessing plant to undertake certain
measures in order to control the air emissions.
¡¡¡¡Tributyl tin (TBT) is an organometallic substance used
in anti-fouling paints. It can cause an effect at low
to sub-nanogram quantities per litre, and is therefore
considered to be one of the most toxic compounds in the
aquatic environment. Its use is now strictly controlled
in most parts of the world. When a vessel is beached,
there will be direct contact between the ship¡¯s hull and
the beach, and some anti-fouling will be ground up. High
concentrations in beach sediments would be expected from
this process. The antifouling residue is deposited in
the sediment or carried away with the current thereby
causing pollution in the marine environment.
¡¡¡¡Isocyanates are often used in spray-painting and polyurethane
coating processes and may be released when hot work is
applied. Occupational exposure can cause respiratory diseases
and asthma. The exposure levels likely to be generated
by ship-dismantling activities are unknown.
4.3 Waste handling
¡¡¡¡Waste from these processes can also have negative impacts
on the environment. Remains generated from the paint and
coating removal processes should be considered hazardous
and should be managed and disposed of accordingly. Procedures
must be identified in the waste management plan for our
Company. This should also identify best-management practices
to prevent or minimize pollution from surface runoff water.
¡¡¡¡The waste management plan will be facility-specific
as different facilities vary in size and location, hydrogeology,
climate, environmental setting, and so on. Paint removal
wastes (including contaminated or residues of solvents
and sludge, solvent-contaminated rags, abrasive residues
and paint chips) that are defined as hazardous waste,
either by appearing on a defined hazardous waste list
or by having hazardous waste characteristics (ignitable,
corrosive, reactive or toxic) are managed according to
the national hazardous waste regulations.
5 Asbestos
5.1 Onboard location
¡¡¡¡Asbestos-containing material (ACM) may be found in thermal
system insulation and on surfacing materials. Engine rooms
usually contain the most asbestos. Some other applications
may also be found. ACM is often visible, but can also
be found underneath other materials that do not contain
asbestos.
5.2 Hazards
¡¡¡¡Asbestos is a natural mineral which is not harmful to
the environment but represents a major health threat.
When ACM is deteriorated or disturbed, asbestos breaks
up into very fine fibers which can be suspended in the
air for long periods and possibly inhaled by workers and
operators at the facility or by people living nearby.
The most dangerous asbestos fibers are too small to be
visible. Once they are inhaled, the fibers can remain
and accumulate in the lungs. Breathing high levels of
asbestos fibers can lead to an increased risk of lung
cancer, mesothelioma (a cancer of the chest and abdominal
linings), and asbestosis (irreversible lung scarring that
can be fatal). The risk of lung cancer and mesothelioma
increases with the number of fibers inhaled. Symptoms
of these diseases do not show up until many years after
exposure. Most people with asbestos-related diseases have
been exposed to elevated concentrations in connection
with their work.
5.3 Waste handling
¡¡¡¡Asbestos is a hazardous waste and should not be re-used
or re-cycled. Maximum precautions include both the protection
of workers when extracting asbestos from the vessel, the
securing of the disposal of asbestos and measures preventing
asbestos from re-entering the market.
¡¡¡¡Our Company has an asbestos disposal
plan in the waste management plan including requirements
associated with the ship¡¯s inventory plans so that asbestos
can be localized, quantified and identified prior to removal.
The plan identifies personnel removing the material and
procedures for both the removal as well as the disposal.
¡¡¡¡Handling of asbestos is monitored by record keeping
as well as by sampling. It is essential to keep the asbestos
wet before and during the removal operations in order
to avoid dispersion of the fine fibers in the air. Asbestos
removal should always be carried out with two people:
one who makes sure the asbestos is wet during the removal
operation and one performing the actual asbestos removal
work.
¡¡¡¡Monitoring includes air-surveillance activities to be
performed in work areas where asbestos is being removed.
The record-keeping includes all measurements taken to
monitor worker-exposure to asbestos.
¡¡¡¡Asbestos removal is carried out only by workers who
have been specially trained to do this type of work. Workers
involved in asbestos removal and disposal must use appropriate
respirators, as well as protective clothing such as overalls,
head coverings, gloves, face shield or vented goggles,
and foot covering. The facility must provide hygiene facilities
for workers, such as decontamination areas (equipment
room, shower area and clean room) and dining areas.
¡¡¡¡If a shipboard inventory containing the details on asbestos
is not available, a survey of asbestos -containing materials
on the ship must be carried out. The inspection should
include determination of location, type and amount of
ACM (localize, identify and quantify). Instead of collecting
samples for asbestos analysis, it might be feasible to
assume that all suspect material is ACM.
¡¡¡¡All ACM must be removed from a ship
being scrapped before any activity that would disturb
the materials is carried out.
¡¡¡¡Once removed from vessel, the asbestos containing waste
(ACM) is disposed of. Asbestos containing waste material
(ACWM) is any waste that contains or is contaminated with
RACM (including equipment and clothing).
¡¡¡¡After wetting, we seal all ACWM in
leak-tight containers while still wet. The containers
are plastic bags (6-mils thick). For bulk wastes that
will not fit into containers without additional breaking,
we must put these wastes into leak-tight wrapping. The
wrapping should be sealed (e.g., with duct tape) while
adequately wet.
¡¡¡¡In all cases, the ACWM should be wet
when contained to prevent the release of asbestos fibers
in case the container or wrapping is broken. An inspector
may check bags or other containers to determine if the
ACWM was kept adequately wet when packaging. One way to
quickly check if this requirement has been met is to lift
the bag. A bag filled with well-wetted material is substantially
heavier and denser. An inspector may also open any bags
to inspect them, most likely using a glove bag or other
emissions control method. The inspector will then properly
reseal the bag, or request that workers do so. An inspector
may also observe trucks picking up asbestos wastes to
see if the bags are handled without bursting or dispersing
asbestos to the atmosphere.
¡¡¡¡Warning labels are placed on all bags,
containers, or wrapping materials containing ACWM. These
labels must be printed in letters of sufficient size and
contrast so that they are easily visible and readable.
The labels must have the wording specified by OSHA:
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| CONTAINS ASBESTOS FIBERS |
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| AVOID CREATING DUST |
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| CANCER AND LUNG DISEASE HAZARD |
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¡¡¡¡Additionally, we label those bags of
ACWM destined to be transported offsite with the name
and location of our company.
¡¡¡¡We control no visible emissions to
the outside air during the collection, packaging, or transporting
of any ACWM by adequately wetting the ACWM to ensure there
are no visible emissions.
¡¡¡¡We inspect if there is any material
on the ground that appears to be ACM (such as white fluff).
We will sample and photograph suspected ACM, as well as
the sources (such as a nearby cable) that it may have
come from.
¡¡¡¡All shipments of ACWM transported off
the facility site are accompanied by a waste shipment
record (WSR). The WSR is a record of the movement and
ultimate disposition of the asbestos waste. Our company,
as a waste generator, keep copies of all WSRs for at least
2 years.
¡¡¡¡We receive a copy of the WSR signed by the disposal
site operator within 35 days to determine the status of
the waste shipment. An inspector will examine the WSRs
to ensure that the records are complete, including all
required signatures for each shipment.
¡¡¡¡Asbestos mixed with cement and confined
in sealed cement box are disposed for landfills in approved
disposal site. ACWM logs and the disposal site records.
Additionally, the inspector checks to see that the asbestos
waste is placed in the disposal site without dispersing
asbestos to the atmosphere, and that the site covers the
asbestos waste daily. If asbestos is removed from a ship
and exhibits any hazardous waste characteristics (e.g.,
toxicity), it is considered a hazardous waste.
6 PCBs
6.1 Onboard location
¡¡¡¡PCBs may be found in both solid and liquid forms in
equipment and materials throughout the ship. Since the
sampling and determination of the presence of PCB's is
a difficult process, a so-called Grey List has been set
up listing suspect materials and equipment.
Grey List of suspected PCB-containing materials
• Cable insulation
• Rubber and felt gaskets
• Thermal insulation material including
fiberglass, felt, foam and cork.
• Transformers, capacitors (also
contained in electronic equipment)
• Voltage regulators, switches,
reclosers, bushings and electromagnets
• Adhesives and tapes
• Oil, including that contained
in electrical equipment and motors, anchor windlasses,
hydraulic systems.
• Surface contamination of machinery
and other solid surfaces
• Oil-based paint
• Caulking
• Rubber isolation mounts
• Foundations mounts
• Pipe hangers
• Light ballasts
• Plasticizers
6.2 Hazards
¡¡¡¡PCBs are toxic and persistent in the environment and
have been shown to cause a number of adverse health effects.
The most carcinogenic PCBs tend to bioaccumulate. Exposure
to PCBs may occur through inhalation, ingestion, or absorption
through the skin. The toxicity of chemicals produced when
PCBs are heated (polychlorinated dibenzofurans and polychlorinated
dibenzo-p-dioxins) is of special concern, as they are
believed to be even more toxic than PCBs themselves.
6.3 Waste handling
¡¡¡¡Workers removing and disposing of PCBs or PCB-containing
materials must use appropriate personal protective clothing
or equipment that protects against dermal contact with
or inhalation of PCBs. Removal and disposal of PCB-containing
materials should be carried out only by workers who have
been specially trained to do this type of work. In cases
where there are several ship -dismantling yards in one
area these specialized workers could be shared by the
dismantling companies.
¡¡¡¡The production of PCBs in the USA ceased in 1979 following
new regulations. In Europe, most countries banned the
manufacturing of PCB in the early 1980s (1978-1982) and
phase-out regulations on use of PCB are in place. A global
campaign aiming at prohibiting all use of PCB is ongoing.
International trade of PCB is regulated in the Rotterdam
Convention and under the Stockholm Convention.
¡¡¡¡Wastes containing PCBs at a concentration level of 50
mg/kg or more are considered hazardous waste by the Basel
Convention. As a precaution, it may be feasible to remove
all known and suspected PCBs and PCB-containing material,
or conduct sampling and chemical analysis of these items,
and if regulated PCB levels are present, dispose of them
according to the criteria set forth in Article 6 of the
Stockholm Convention.
¡¡¡¡PCBs or PCB items to be stored must
be placed in proper containers, covered and labelled.
Temporary storage facilities for PCB-containing waste
must have a floor-covering that prevents penetration of
PCBs and a curbing that provides sufficient containment
volume in the case of a spill, roof and walls that prevent
rainwater from reaching the wastes, and no floor drains
or other openings that would allow liquids to flow from
the area. Disposal requireme nts may be dependent upon
the nature of the source and its concentration.
7. Other waste streams
7.1 Radiation
sources.
¡¡¡¡Radioactive material may be present
on board a ship in liquid level indicators, smoke detectors
or emergency signs. These sources generate low -level
radioactive waste, but handling and disposal of such waste
is usually strictly regulated. Ionizing radiation is hazardous
to human health and the environment and can cause severe
forms of cancer and/ or damage to genetic material endangering
future generations. Any release of radioactive material
could increase the radiation exposure to the population
and must therefore be avoided.
¡¡¡¡We request ship owners to discharge
all radioactive materials before we decide to purchase
such old ship.
7.2 Timber
¡¡¡¡Timber can be found in furniture or walls, and timber
may for example contain preservation or paint that could
have an adverse effect on the environment. The timber
should be treated according to national regulations and
should be taken care of by approved waste companies.
7.3 Polyvinyl chloride (PVC)
¡¡¡¡PVC is used in a wide variety of products for different
applications and is commonly found in cables, floor coverings
and plastic devices of different types. PVC products may
contain more than 50% chlorine, and may contain environmentally
hazardous additives. A complex mixture of fumes and gases
is generated when PVC is burned, depending on the oxygen
availability and other fire conditions. This includes
carbon monoxide and dioxins. Indeed all open burning may
generate toxic gases and should therefore be prohibited,
but PVC is of particular concern because of the chlorine
content. Also, large quantities of hydrogen chloride gas
are generated when PVC is burned. The hydrogen chloride
gas combines with water to form hydrochloric acid in the
lungs.
7.4 Batteries
¡¡¡¡Batteries can contain heavy metals such as Pb, Cd and
Ni. Lead-acid batteries also contain sulphuric acid, which
is corrosive and can cause severe burns. Batteries can
be in flashlights, mobile radios and electrical equipment,
but the largest volume of batteries (lead-acid batteries)
is found in radio applications, intercoms, fire alarms,
emergency start equipment and lifeboats. Batteries in
working order will most often be sorted and sold for reuse.
Lead alone represents a considerable value, and there
is therefore reason to believe that batteries are recycled
regardless of their condition. If batteries are undamaged,
they will not have an environmental effect. However, the
improper storage or disposal of batteries can cause a
threat to human health and the environment.
7.5 Freon
¡¡¡¡Freon is a Du Pont trade name for chlorofluorocarbons
(CFC), which are compounds consisting of chlorine, fluorine
and carbon. CFCs are non-toxic, non-flammable compounds
that are stable in the troposphere, but in the stratosphere,
can be broken down by UV light and deplete the ozone layer.
CFCs are used as refrigerants, solvents and foam-blowing
agents. Shipborne CFCs have been believed to contribute
to up to 10% of global emissions.
7.6 Other chemicals
¡¡¡¡Other chemicals/ substances/ components that may require
special handling are for example:
• Antifreeze fluids
• Solvents/ thinners
• Battery electrolyte
• Evaporator dosing and de-scaling
acids
• Corrosion inhibitor
• Compressed gases (acetylene,
propane and butane)
• Plastics, as covered by MARPOL
• Boiler/ water treatment chemicals
• Kerosene/ White Spirit
• Anti-freeze compounds
• Engine additives
• Flame retardants
• Miscellaneous chemicals, such
as alcohols, methylated spirits, epoxy resins, etc.
¡¡¡¡The chemicals/ substances/ components
above may have negative effects on the environment. They
may represent a market value and some are therefore sold
on for further use. Their characteristics are not addressed
any further in these guidelines.
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